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Technical Physics

Open systems: mass and energy balances, turbines, compressors and valves

The control volume, mass balance, the first law for open systems with proof and enthalpy, turbine, compressor, nozzle, valve, heat exchanger and PC ventilation.

In Physics 1 the first law of thermodynamics was applied to closed systems, such as a gas in a cylinder. Real machines, however, have matter flowing through them: air goes in and out of a compressor, steam through a turbine, water through a heat exchanger. In this lesson we write the mass and energy balances for open systems and apply them to the most common plant components.

The control volume

A region of space is chosen, the control volume, bounded by a surface through which matter can enter and leave. Heat \dot Q (positive if entering) and work \dot W (positive if leaving, for example through a rotating shaft) also cross the boundary.

Control volume with an inlet section and an outlet section, heat and work
The fluid enters through section 1 with its own flow rate, enthalpy, velocity and height and leaves through section 2. Thermal power Q enters through the dashed boundary and mechanical power W leaves through the machine’s shaft.

The mass balance

In steady state (nothing changes in time inside the volume) the mass entering each second equals the mass leaving:

    \[ \dot m = \rho_1 A_1 v_1 = \rho_2 A_2 v_2 \]

where A is the cross-section area and v the average velocity. For a liquid (constant \rho) it reduces to A_1v_1 = A_2v_2: where the pipe narrows, the fluid speeds up.

The energy balance

Theorem (first law for open systems in steady state). With one inlet and one outlet:

    \[ \dot Q - \dot W = \dot m\left[(h_2 - h_1) + \frac{v_2^2 - v_1^2}{2} + g(z_2 - z_1)\right] \]

where h = u + pv_s is the specific enthalpy (u internal energy, v_s specific volume).

Proof. In steady state the energy in the volume does not change, so the energy entering each second equals the energy leaving. Each kilogram of fluid carries internal, kinetic and potential energy, u + v^2/2 + gz. In addition, to push a kilogram into the volume, the upstream fluid does work equal to pressure times volume displaced, p_1v_{s1}; at the outlet the fluid in the volume does work p_2v_{s2} on the fluid downstream. This flow work adds to the internal energy and gives the enthalpy. Balancing:

    \[ \dot Q + \dot m\left(u_1 + p_1v_{s1} + \frac{v_1^2}{2} + gz_1\right) = \dot W + \dot m\left(u_2 + p_2v_{s2} + \frac{v_2^2}{2} + gz_2\right) \]

which rearranged is the statement. ∎

Enthalpy is therefore the natural quantity for open systems: that is why steam and refrigerant tables always list it.

Plant components

In most cases some terms are negligible, and the balance becomes very simple.

  • Turbine (adiabatic, negligible kinetic and potential energy): \dot W = \dot m(h_1 - h_2). The fluid gives up enthalpy and the machine produces work. Example: 10 kg/s of steam entering at h_1 = 3230 kJ/kg and leaving at h_2 = 2550 kJ/kg give 10\cdot 680 = 6800 kW, 6.8 MW.
  • Compressor and pump: the same with the opposite sign, work goes in: \dot W_{in} = \dot m(h_2 - h_1).
  • Nozzle (no work, adiabatic): enthalpy turns into kinetic energy, v_2 = \sqrt{v_1^2 + 2(h_1 - h_2)}. With a 50 kJ/kg drop and negligible initial velocity, v_2 = \sqrt{2\cdot 50\,000} \approx 316 m/s.
  • Throttling valve (no work, no heat, similar velocities): h_2 = h_1. Pressure falls but enthalpy stays the same; for a vapour or a refrigerant this means strong cooling, and it is the heart of refrigerators.
  • Heat exchanger: two fluids separated by a wall; the heat given up by one is gained by the other, \dot m_h(h_{h1} - h_{h2}) = \dot m_c(h_{c2} - h_{c1}). With constant specific heat, \dot Q = \dot m\,c_p\,\Delta T.

A case close to electronics

A PC dissipates 300 W, removed by an air flow. If the air may warm up by 10 °C between the case inlet and outlet, the heat exchanger balance gives the required flow: \dot m = \dot Q/(c_p\Delta T) = 300/(1005\cdot 10) \approx 0.03 kg/s, that is about 25 litres of air per second (with a density of 1.2 kg/m³). This is the figure fans are chosen from.

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